DESIGNING RESIN- RUBBER SOLE COMPOUNDS FOR USE IN LOCAL SHOE MANUFACTURING INDUSTRY R.R.M.S.K RANATUNGA . This thesis was submitted to the department of Chemical Engineering of University of Moratuwa in partial fulfilment of the requirements for the Degree of M.Sc. in Polymer Technology. University of Moratuwa 77717 Department of Chemical Engineering University of Moratuwa ^ M ^ o € ^ 1 ^ • Sri Lanka "7 "7 7 / 7 February 2003. 11111 ' v . II ACKNOWLEDGEMENTS I wish to thank the management of Arpitalian Compact Soles (Pvt) Ltd for giving me an opportunity to follow M.Sc course in Polymer Technology and also facilitating for me to conduct Research project. My sincere thanks should go to Mr. Kithsiri Wijesundara former General Manager of Arpitalian for encouraging me and granting leaves for the studies. I would like to express my deepest gratitude to my supervisors Mr. K. Subramaniam, M.Sc. course Coordinator, Department of Chemical Engineering, University of Moratuwa and Mr. Wasantha Abeysirigunawardena, General Manager (Research and Development), Richard Pieris Export Ltd, for their relentless guidance and unflagging interest shown right throughout my research projects as well as course of study. My deep appreciation of the generous gesture of thanks goes out all my friends and colleagues who helped me in numerous ways in the field. I express my gratitude to Mr. S. K. Moragoda, for his sincere assistance given throughout my research project for carrying out all laboratory trials and preparing laboratory-testing reports. I owe gratitude to my loving wife and family members for their constant help extended to me in achieving the goal. Last, but not least. 1 wish to place on record my gratitude and thanks to all other staff of Arpitalian Compact Soles (Pvt) Ltd., too numerous to individually mention, for their assistance and encouragement rendered to me make this a success. I l l ABSTRACT Natural rubber and Reclaimed rubber based resin- rubber soling sheets compounded with various cheap rubber ingredients were made and evaluated in this work for their use in local shoe manufacturing industry'. In the experimental work, natural rubber and reclaimed rubber compounds formulated with different ingredients were prepared and moulded into sheets by compression moulding technique. The surfaces of the sheets were abraded and then crated with different flexible colour-paints. The painted (Coloured) sheets produced were then tested and evaluated for resin- rubber shoe sole sheets. The investigation reveals that the compounds containing the peptised natural rubber (SLR 20) and reclaimed rubber (DSI-Super fine grade) are found to be the most appropriate compounds for the production of resin-rubber soles in the local rubber industry. C O N T E N T S Acknowledgement II Abstract III CHAPTER 1 INTRODUCTION 1.1 Introduction 2 1.2 Major components of a shoe 3 1.3 Aim of the project 4 1.4 Method of approach and materials 4 CHAPTER 2 HISTORICAL REVIEW OF SOLING MATERIALS 2.1 Historical review 6 2.2 Shoe Soling Materials and their main features and applications 6 2.3 World's Usage of soling materials 8 2.4 Density of the soling materials 9 2.5 Physical properties of standard resin soling 10 2.6 Survey on resin rubber sole compounds used in Sri Lankan industries 12 CHAPTER 3 EXPERIMENTAL 3.1 Materials 19 3.2 Choice of rubber compound formulation 25 3.3 Methods employed 30 3.4 Testing methods 34 CHAPTER 4 RESULTS AND DISCUSSION 4.1 Results and discussion 39 4.2 Conclusion 48 4.3 Future work 49 REFERENCES 50