A molecular dynamics study of thermal conductivity and viscosity in colloidal suspensions: From well-dispersed nanoparticles to nanoparticle aggregates

dc.contributor.authorSomarathna, C
dc.contributor.authorSamaraweera, N
dc.contributor.authorJayasekara, S
dc.contributor.authorPerera, K
dc.date.accessioned2023-11-29T07:30:09Z
dc.date.available2023-11-29T07:30:09Z
dc.date.issued2023
dc.description.abstractThis study investigates the microscopic transport behavior of nanofluids addressing some debatable points including the anomalous thermal conductivity ( ), against the predictions of classical effective medium theories. International Nanofluid Property Benchmark Exercise (INPBE) [J. Buongiorno et al., J. Appl. Phys. 106 (2009) 094312] has shown that no such anomaly found in well-dispersed nanofluids after conducting experiments for range of different types of nanofluids. However, a number of molecular dynamics based studies reported otherwise making inconsistent conclusion with INPBE. In this work, it is argued that the over predicted values reported in previous computational studies can be attributed to the ill-defined partial enthalpy formulation of the Green-Kubo method for multicomponent systems. Present study begins by addressing this issue via non-equilibrium molecular dynamics and shows that the results are in agreement with the conclusions of INPBE. Further, it is shown that the contribution of potential micro-mechanisms such as micro-convection due to Brownian motion, and the solid-like liquid layering are either absent or suppressed by the interface thermal resistance. The observed decreasing trend of viscosity enhancement to thermal conductivity enhancement ratio ( ) with increasing particle size indicates the improved heat transfer performance in nanofluids with larger nanoparticles. The effect of nanoparticle aggregation, the proposed originative mechanism of anomalous , is evaluated arranging nanoparticles as chain-like structures. A 67% improvement in is achieved with negligible viscosity variation. This rapidly reduces indicating better heat transfer performance with the presence of conductive paths due to the aggregation or in general extended nanostructures.en_US
dc.identifier.citationSomarathna, C., Samaraweera, N., Jayasekara, S., & Perera, K. (2023). A molecular dynamics study of thermal conductivity and viscosity in colloidal suspensions: From well-dispersed nanoparticles to nanoparticle aggregates. Applied Thermal Engineering, 229, 120651. https://doi.org/10.1016/j.applthermaleng.2023.120651en_US
dc.identifier.databaseScienceDirecten_US
dc.identifier.doihttps://doi.org/10.1016/j.applthermaleng.2023.120651en_US
dc.identifier.issn1359-4311en_US
dc.identifier.journalApplied Thermal Engineeringen_US
dc.identifier.pgnos120651 (1-12)en_US
dc.identifier.urihttp://dl.lib.uom.lk/handle/123/21787
dc.identifier.volume229en_US
dc.identifier.year2023en_US
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.subjectNanofluiden_US
dc.subjectNanoparticleen_US
dc.subjectThermal conductivityen_US
dc.subjectViscosityen_US
dc.subjectMolecular dynamicsen_US
dc.titleA molecular dynamics study of thermal conductivity and viscosity in colloidal suspensions: From well-dispersed nanoparticles to nanoparticle aggregatesen_US
dc.typeArticle-Full-texten_US

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